By default, FreeFileSync will show a progress dialog during synchronization and will wait while the results dialog is shown.
If the progress dialog is not needed, enable checkbox Run minimized. This will also skip the results dialog at the end.
Alternatively, if you want to see the progress, but not to wait at the results dialog, it's sufficient to only select the On completion action Close progress dialog.
Note
Even if the progress dialog is not shown at the beginning, you can make it visible later during
synchronization by double-clicking the FreeFileSync icon in the notification area.